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Ionic Equilibrium

Chemistry · Weak 36% · Revised by the coach 14 Nov: Added the trap from the buffer doubt

Chapter

1 · Formulas and when each holds

  • pH = −log[H⁺]; pH + pOH = 14 at 25 °C.
  • Weak acid: [H⁺] = √(Ka·C), when the degree of dissociation is small.
  • Buffer (Henderson): pH = pKa + log([salt]/[acid]).
  • Salt of weak acid and strong base: pH = 7 + ½(pKa + log C).

2 · Question types and the first step

  • Buffer questions: find the ratio of salt to acid before anything else.
  • Solubility product: write s in terms of Ksp from the formula of the salt.

3 · Traps

Common ion: solubility falls in a solution that already holds one of the ions.

Buffer on dilution: he diluted the acid alone. Rule: dilution changes salt and acid equally, so the ratio and the pH stay.

4 · My additions

  • Check the temperature before using 14.

Chemical Bonding

Chemistry · Shaky 53% · Saved 3 Nov: First version, from the class module

Chapter

1 · Formulas and when each holds

  • Bond order (MOT) = ½(bonding − antibonding electrons).
  • Hybridisation: count σ bonds and lone pairs on the central atom.
  • Dipole moment is a vector: symmetric shapes cancel.

2 · Question types and the first step

  • Shape questions: count electron pairs, then name the geometry, then the shape.
  • Magnetic behaviour: write the MO filling and look for unpaired electrons.

3 · Traps

O₂ is paramagnetic: two unpaired electrons in π* orbitals.

4 · My additions

  • s-p mixing changes the order for B₂, C₂, N₂.

Coordination Compounds

Chemistry · Shaky 53%

Chapter

No note yet.

Alkyl Halides

Chemistry · Weak 33%

Chapter

No note yet.